Weak ergodicity breaking and quantum scars in constrained quantum systems

The success of statistical mechanics in describing complex quantum systems rests upon typicality properties such as ergodicity. Both integrable systems and the recently discovered many-body localisation show that these assumptions can be strongly violated in either finely tuned cases, or in the presence of quenched disorder. In this thesis, we uncover a qualitatively different form of ergodicity breaking, wherein a small number of atypical eigenstates are embedded throughout an otherwise thermalising spectrum. We call this a many-body quantum scar, in analogy to quantum scars in single-particle quantum chaos, where quantum scarred eigenfunctions concentrate around associated periodic classical trajectories. We demonstrate that many-body quantum scars can be found in an unusual model recently realised in a 51 Rydberg atom quantum simulator. The observed coherent oscillations following in a certain quench experiment are a consequence of the quantum scar. At the same time, the level statistics rules out conventional explanations such as integrability and many-body localisation. We develop an approximate method to construct scarred eigenstates, in order to describe their structure and physical properties. Additionally, we find a local perturbation which makes these non-equilibrium properties much more pronounced, with near perfect quantum revivals. At the same time the other eigenstates remain thermal. Our results suggest that many-body quantum scars forms a new class of quantum dynamics with unusual properties, which are realisable in current experiments

LEADING INDICATORS FOR REGIONAL COTTON RESPONSE: STRUCTURAL AND TIME SERIES MODELING RESULTS

Resurging southeastern cotton production compels better cotton acreage forecasts for planning seed, chemical, and other input requirements. Structural models describe leading acreage response indicators, and forecasts are compared time-series models. Cotton price, loan rate, deficiency payments, lagged corn acreage, the PIK program, and previous cotton yield significantly influence response.Crop Production/Industries,

LEADING INDICATORS OF REGIONAL COTTON ACREAGE RESPONSE: STRUCTURAL AND TIME SERIES MODELING RESULTS

Resurgent cotton production compels better acreage forecasts for planning seed, chemical, and other input requirements. Structural models describe leading acreage response indicators, and forecasts are compared to time-series models. Cotton price, loan rate, deficiency payments, lagged corn acreage, the PIK program, and previous cotton yield significantly influence cotton acreage response.resurgent cotton production, cotton acreage, Crop Production/Industries,

Irrational Beliefs and Choking under Pressure: A Preliminary Investigation

Researchers who examine existing models of choking under pressure are beginning to explore the antecedents that predispose individuals to increased anxiety. Irrational beliefs (IBs) may be one such antecedent to “choking”, given that irrational beliefs are closely associated with anxiety intensity. This study aimed to investigate whether IBs influenced anxiety and performance under pressure. Experienced Australian football players (N=35) completed an IBs questionnaire prior to an Australian football set shot experiment with low- and high-pressure. During both pressure conditions, participants completed a state anxiety questionnaire prior to completing 15 set shots on goal. Results indicated that cognitive and somatic anxiety increased from low- to high-pressure. For somatic anxiety, an IBs main effect approached significance, indicating higher somatic anxiety with increases in IBs. A marginally significant Condition main effect was found for performance, which decreased from low- to high-pressure, with no other effects for performance evident. Follow-up correlation analysis of seven athletes who likely experienced choking (i.e., greater than 15-point performance decrease) indicated a strong negative correlation between IBs and change in performance from low- to high-pressure. Further analyses for “chokers” indicated a significant IBs x Condition interaction, with performance tending to increase with increasing IBs under low-pressure and decrease with increasing IBs under high-pressure. This study provides initial, tentative support that IBs associated with performance trends of “chokers” under different pressure conditions may be dissimilar to those of “underperformers” or “clutch” performers. Applied implications for sport psychologists working with athletes are discussed

New nickel(II) and iron(II) helicates and tetrahedra derived from expanded quaterpyridines

As an extension of prior studies involving the linear quaterpyridine ligand, 5,5'''-dimethyl-2,2':5',5'':2'',2'''-quaterpyridine 1, the synthesis of the related expanded quaterpyridine derivatives 2 and 3 incorporating dimethoxy-substituted 1,4-phenylene and tetramethoxy-substituted 4,4'-biphenylene bridges between pairs of 2,2'-bipyridyl groups has been carried out via double-Suzuki coupling reactions between 5-bromo-5'-methyl-2'-bipyridine and the appropriate di-pinacol-diboronic esters using microwave heating. Reaction of 2 and 3 with selected Fe(II) or Ni(II) salts yields a mixture of both [M2L3]4+ triple helicates and [M4L6]8+ tetrahedra, in particular cases the ratio of the products formed was shown to be dependent on the reaction conditions; the respective products are all sufficiently inert to allow their chromatographic separation and isolation. Longer reaction times and higher concentrations were found to favour tetrahedron formation. The X-ray structures of solvated [Ni2(2)3](PF6)4, [(PF6) ⊂ Fe4(2)6](PF6)7, [Fe4(3)6](PF6)8 and [Ni4(3)6](PF6)8 have been determined, while the structure of the parent Fe(II) cage in the series, [(PF6) ⊂ Fe4(1)6](PF6)7, was reported previously. The internal volumes of the Fe(II) tetrahedral cages have been calculated and increase from 102 Å3 for [Fe4(1)6]8+ to 227 Å3 for [Fe4(2)6]8+ to 417 Å3 for [Fe4(3)6]8+ and to an impressive 839 Å3 for [Ni4(3)6]8+. The corresponding void volume in the triple helicate [Ni2(2)3]4+ is 29 Å3

Grain size and organic carbon controls polyaromatic hydrocarbons (PAH), mercury (Hg) and toxicity of surface sediments in the River Conwy Estuary, Wales, UK

The Conwy estuary was evaluated for sediment quality. Microtox bioassay revealed 38 of 39 sites were non-toxic. Hg ranged from 0.001 to 0.153 μg kg−1, mean 0.026 mg kg−1, Σ16 PAH from 18 to 1578 μg kg−1, mean 269 μg kg−1, Σ22 PAH, 18 to 1871 μg kg−1 mean to 312 μg kg−1, two sites had high perylene relative to ΣPAH. Σ22PAH correlated positively with TOC, clay and silt (R2 0.89, 0.92, 0.90) and negatively with sand. Multivariate statistics, delineated four spatial (site) and five variable (measurements) clusters. Spatial clustering relates to sediment grain size, in response to hydrodynamic processes in estuary; fine (clay to silt) sized sediments exhibit the highest Hg and PAH content, because these components partitioned into the fine fraction. Comparison to national and international environmental standards suggests Hg and PAH content of Conwy sediments are unlikely to harm ecology or transfer up into the human food chain

Quantification of diesel injector dribble using 3D reconstruction from x-ray and DBI imaging

[EN] Post-injection dribble is known to lead to incomplete atomisation and combustion due to the release of slow moving, and often surface-bound, liquid fuel after the end of the injection event. This can have a negative effect on engine emissions, performance, and injector durability. To better quantify this phenomenon we present a new image processing approach to quantify the volume and surface area of ligaments produced during the end of injection, for an ECN ‘Spray B’ 3-hole injector. Circular approximation for cross-sections was used to estimate three-dimensional parameters of droplets and ligaments. The image processing consisted in three stages: edge detection, morphological reconstruction, and 3D reconstruction. For the last stage of 3D reconstruction, smooth surfaces were obtained by computation of the alpha shape which represents a bounding volume enveloping a set of 3D points. The object model was verified by calculation of surface area and volume from 2D images of figures with well-known shapes. We show that the object model fits non-spherical droplets and pseudo-cylindrical ligaments reasonably well. We applied our processing approach to datasets generated by different research groups to decouple the effect of gas temperature and pressure on the fuel dribble process. High-speed X-ray phase-contrast images obtained at room temperature conditions (297 K) at the 7-ID beamline of the Advanced Photon Source at Argonne National Laboratory, together with diffused back-illumination (DBI) images captured at a wide range of temperature conditions (293-900 K) by CMT Motores Térmicos, were analysed and compared quantitatively.This work was supported by the UK’s Engineering and Physical Science Research Council [grants EP/K020528/1 and EP/M009424/1], and BP Formulated Products Technology. The authors acknowledge the support of this work from CMT Motores Térmicos (Universitat Politècnica de València, Spain). Parts of this research were performed at the 7-ID beam line of the Advanced Photon Source at Argonne National Laboratory. Use of the APS is supported by the U.S. Department of Energy (DOE) under Contract No. DEAC02-06CH11357. This research was partially funded by DOE's Vehicle Technologies Program, Office of Energy Efficiency and Renewable Energy. The authors would like to thank Team Leaders Gurpreet Singh and Leo Breton for their support of this workSechenyh, V.; Turner, J.; Sykes, D.; Duke, D.; Swantek, A.; Matusik, K.; Kastengren, A.... (2017). Quantification of diesel injector dribble using 3D reconstruction from x-ray and DBI imaging. En Ilass Europe. 28th european conference on Liquid Atomization and Spray Systems. Editorial Universitat Politècnica de València. 216-223. https://doi.org/10.4995/ILASS2017.2017.4742OCS21622

First Light And Reionisation Epoch Simulations (FLARES) XIII: the Lyman-continuum emission of high-redshift galaxies

The history of reionisation is highly dependent on the ionising properties of high-redshift galaxies. It is therefore important to have a solid understanding of how the ionising properties of galaxies are linked to physical and observable quantities. In this paper, we use the First Light and Reionisation Epoch Simulations (FLARES) to study the Lyman-continuum (LyC, i.e. hydrogen-ionising) emission of massive ($M_*>10^8\,\mathrm{M_\odot}$) galaxies at redshifts $z=5-10$. We find that the specific ionising emissivity (i.e. intrinsic ionising emissivity per unit stellar mass) decreases as stellar mass increases, due to the combined effects of increasing age and metallicity. FLARES predicts a median ionising photon production efficiency (i.e. intrinsic ionising emissivity per unit intrinsic far-UV luminosity) of $\log_{10}(\xi_{\rm ion}\rm{/erg^{-1}Hz})=25.40^{+0.16}_{-0.17}$, with values spanning the range $\log_{10}(\xi_{\rm ion}\rm{/erg^{-1}Hz})=25-25.75$. This is within the range of many observational estimates, but below some of the extremes observed. We compare the production efficiency with observable properties, and find a weak negative correlation with the UV-continuum slope, and a positive correlation with the OIII equivalent width. We also consider the dust-attenuated production efficiency (i.e. intrinsic ionising emissivity per unit dust-attenuated far-UV luminosity), and find a median of $\log_{10}(\xi_{\rm ion}\rm{/erg^{-1}Hz})\sim25.5$. Within our sample of $M_*>10^8\,\mathrm{M_\odot}$ galaxies, it is the stellar populations in low mass galaxies that contribute the most to the total ionising emissivity. Active galactic nuclei (AGN) emission accounts for $10-20$ % of the total emissivity at a given redshift, and extends the LyC luminosity function by $\sim0.5$ dex.Comment: 18 pages, 17 figures, submitted to MNRA

First Light And Reionisation Epoch Simulations (FLARES) XI: [OIII] emitting galaxies at 5<z<105<z<10

JWST has now made it possible to probe the rest-frame optical line emission of high-redshift galaxies extending to z~9, and potentially beyond. To aid in the interpretation of these emerging constraints, in this work we explore predictions for [OIII] emission in high-redshift galaxies using the First Light and Reionisation Epoch Simulations (FLARES). We produce predictions for the [OIII] luminosity function, its correlation with the UV luminosity, and the distribution of equivalent widths (EWs). We also explore how the [OIII] EW correlates with physical properties including specific star formation rate, metallicity, and dust attenuation. Our predictions are largely consistent with recent observational constraints on the luminosity function, average equivalent widths, and line ratios. However, they fail to reproduce the observed tail of high-EW sources and the number density of extreme line emitters. Possibilities to explain these discrepancies include an additional source of ionising photons and/or greater stochasticity in star formation in the model or photometric scatter and/or bias in the observations. With JWST now rapidly building larger samples and a wider range of emission lines the answer to this remaining discrepancy should be available imminently.Comment: 15 pages, accepted for publication in MNRAS, minor changes from original versio

Phase variation mediates reductions in expression of surface proteins during persistent meningococcal carriage

Asymptomatic and persistent colonization of the upper respiratory tract by Neisseria meningitidis occurs despite elicitation of adaptive immune responses against surface antigens. A putative mechanism for facilitating host persistence of this bacterial commensal and pathogen is alterations in expression of surface antigens by simple sequence repeat (SSR)-mediated phase variation. We investigated how often phase variation occurs during persistent carriage by analyzing the SSRs of eight loci in multiple isolates from 21 carriers representative of 1 to 6 months carriage. Alterations in repeat number were detected by a GeneScan analysis and occurred at 0.06 mutations/gene/month of carriage. The expression states were determined by Western blotting and two genes, fetA and nadA, exhibited trends toward low expression states. A critical finding from our unique examination of combinatorial expression states, “phasotypes,” was for significant reductions in expression of multiple phase-variable surface proteins during persistent carriage of some strains. The immune responses in these carriers were examined by measuring variant-specific PorA IgG antibodies, capsular group Y IgG antibodies and serum bactericidal activity in concomitant serum samples. Persistent carriage was associated with high levels of specific IgG antibodies and serum bactericidal activity while recent strain acquisition correlated with a significant induction of antibodies. We conclude that phase-variable genes are driven into lower expression states during long-term persistent meningococcal carriage, in part due to continuous exposure to antibody-mediated selection, suggesting localized hypermutation has evolved to facilitate host persistence